A novel Ag–CuAlO2 sealant for reactive air brazing of 3YSZ and AISI 310S

Based on reactive air brazing (RAB), we designed a new type of sealant (Ag–xCuAlO₂) for joining 3 mol.% yttria-stabilized zirconia (YSZ) ceramics and AISI 310S stainless steel. The CuAlO₂ content affected the wettability of the sealant on the YSZ surface, and the joints had a high shear strength when Ag–2 wt.%CuAlO₂, which had a small contact angle on the YSZ substrate, was used as the sealant. In addition, the thickness of the oxide layer was reduced compared to that for the Ag–CuO sealant. The effects of the processing parameters on the microstructure and shear strength of the joints were investigated, and the as-brazed joints reached their highest shear strength (93.7 MPa) when brazed at 1040 °C for 30 min. After high-temperature oxidation at 800 °C for 200 h, the shear strength of the joints remained at 50 MPa, and no apparent change in the microstructure was observed, proving that the joints possessed excellent oxidation resistance.     

40000m~3/h空分设备主换热器的设计及制造

通过对进口 4 0 0 0 0m3 /h空分设备主换热器进行结构分析及对比模拟计算 ,用国产传热翅片进行设计、采用真空钎焊工艺制造的主换热器 ,经并网运行 ,设计指标优于原空分设备 ,为今后成套大型空分设备板翅式换热器国产化设计、制造创造了条件。     

火焰筒后段通道组件真空钎焊

对钣金涨型结构件--XX火焰筒后段通道组件的真空钎焊进行了研究,详细介绍了钎料预置和规范参数选择,其钎料预置采用粘带、粉、膏状镍基钎料Amdry915联合运用.实验结果表明,采用所制定的钎焊规范,钎焊出了满足要求的火焰筒,并已用于批生产.     

铝制板翅式换热器真空钎接下凹原因探讨

基于铝制板式体的基本结构,提出了板式体真空钎接下凹形成原理,并在此基础上分析了影响板式体钎接下凹的因素:材料的影响、天气的影响、板式体外形的影响及钎接温度的影响。最后针对下凹问题,提出了几点改进意见。     

超声波辅助合成离子液体及其性能研究

以超声波辅助法合成了离子液体1丁-基-3-甲基咪唑氟硼酸盐([BM Im]BF4),对产物进行了光谱分析、电导率和粘度测定,并考察了其酯化反应的催化性能.实验结果表明:该合成方法具有合成条件简单、反应时间短、能耗低、易纯化等优点.[BM Im]BF4在甲醇中的最大紫外吸收波长为213 nm,IR图谱与文献报道吻合;分别以丙酮、无水乙醇和乙酸乙酯为溶剂,测得[BM Im]BF4的极限摩尔电导率分别为237.94 S·cm2·mol -1、47.22 S·cm2·mol-1和1.5411 S·cm2·mol-1.     

高温钎料PdCu-Ti在氧化铝陶瓷上的润湿性及界面反应

本文采用座滴法试验研究了合金系统ＰｄＣｕ－Ｔｉ在Ａｌ２Ｏ３上润湿性的变化规律，探讨了界面冶金及结合等行为，运用热力学理论对结果进行了分析，随Ｔｉ含量的增加及Ｐｄ含量的减少润湿角逐渐降低，Ｔｉ的加入使界面发生了一个双重变化；液相侧富氧，钛吸收层的生成及随后的固相侧氧化钛的生成，只有界面上生成一氧化钛，才能有较好的润湿行为和较强的结合力。     

LD2铝合金的钎焊工艺

对LD2的铝合金零件进行了钎焊工艺分析，采取合理的措施及相关对策，成功地进行了钎焊，并达到了相应的技术要求。     

电子束钎焊温度模糊控制系统

将被焊工件温度模糊控制技术应用于电子束扫描钎焊中,所研发的系统集成了电子束焊接过程控制、电子束扫描轨迹控制、工件温度模糊控制、焊接数据高速采集与存储等多项功能.通过扫描轨迹的编辑与控制,可以适应各种形状曲线钎焊缝的温度场要求;在电子束对工件进行扫描加热的同时,通过温度采集装置实时得到被焊工件的温度信号并与设定值进行对比从而得到温度偏差及偏差的变化率作为模糊控制器的两个输入变量,以模糊控制器输出控制量调节电子束流大小,从而实现钎焊温度的闭环控制.控制系统具有响应速度快、稳定时间短、稳态误差小、超调量小等特点,表明在电子束钎焊过程中采用模糊控制技术可以得到非常理想的控制效果.     

Joining of metal bars by a new process of transformation-diffusion brazing

Within the bonded interface of metal bars joint produced by conventional solid state bonding process （ such as flash welding, resistance butt welding, friction welding and so on）, the inclusions are often present, which degrade the ductility of joint. A new process of transformation-diffusion brazing is proposed, in which an amorphous foil containing melting point depressant is preplaced between the interfaces to be joined, and the assembly is repeatedly heated/cooled without holding time at peak temperature. A low carbon steel bars, BNi-2 amorphous foil and resistance butt welding machine were used. The results show that surfuce contamination can be disrupted by the dissolution of base metal into molten interlayer in comparison with conventional process, and the ductility of joint can be improved by increasing the times of temperature cycles on line. In addition, transformation-diffusion brazing can be done with relatively simple and inexpensive system in comparison with transient liquid phase bonding.     

热处理工艺对截齿钎焊接头强度的影响

为获得采煤机用截齿钎焊接头的优良性能，作者研究了钎焊后热处理工艺参数对钎缝抗剪强度的影响。试验表明，高温区停留时间在保证钎焊时钎料充分熔化的前提下越短越好；冷却速度对接头的强度有较大影响，一般情况下，钎焊后由880℃冷却到200℃的时间应控制在5～20min之间；回火温度在350～450℃之间抗剪强度有低谷区。截齿钎焊采用HL105钎料，配以合适的钎剂能获得较理想的接头性能。